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Haven't seen any pyrolusite flotation done, however no doubt possible based on other 'oxide' flotation systems. Just need to identify the surface charge (IEP, ZPC) of the manganese mineral as a function of pH, look up the surface charge of the gangue minerals at the various pHs and then select your collector(s) (anionic vs. cationic).

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The flotation of low-grade manganese ore using a novel linoleate hydroxamic acid. ... and the characteristic structure determines the strong chelating ability of the hydroxamic acid with metal ions ... The manganese ore samples used in the flotation studies originated from Changsha, China.

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At present, China oxide ore treatment process, usually broken ore to 6 ~ 0mm or 10 ~ 0mm, then grouped choose to send shaker jigging coarse level and fine level . ore beneficiation equipment, mostly Haz reciproing Jig and 6S type shaker . Magnetic – flotation Process: Currently used magnetic – just Zunyi manganese ore flotation process .

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